A proof of Clausius' theorem for time reversible deterministic microscopic dynamics.

نویسندگان

  • Denis J Evans
  • Stephen R Williams
  • Debra J Searles
چکیده

In 1854 Clausius proved the famous theorem that bears his name by assuming the second "law" of thermodynamics. In the present paper we give a proof that requires no such assumption. Our proof rests on the laws of mechanics, a T-mixing property, an ergodic consistency condition, and on the axiom of causality. Our result relies on some recently derived theorems, such as the Evans-Searles and the Crooks fluctuation theorems and the recently discovered relaxation and dissipation theorems.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 134 20  شماره 

صفحات  -

تاریخ انتشار 2011